IJCRRI Journ Cur Res ReInternational Journal of Current Research and ReviewI Journ Cur Res Re2231-21960975-5241Radiance Research Academy1899General SciencesKINETICS AND MECHANISM OF OXIDATION OF BENZOPHENONE OXIME BY BISPYRIDINE SILVER (I) DICHROMATE DharmarajaJ.S.VadivelA.Kandasamy69This article is copyright of Popeye Publishing, 20092009This is an open-access article distributed under the terms of the Creative Commons Attribution (CC BY 4.0) Licence. You may share and adapt the material, but must give appropriate credit to the source, provide a link to the licence, and indicate if changes were made.

The oxidation of Benzophenoneoxime by Bispyridine silver (I) dichromate (BPSDC) has been studied in 50% (v/v) aqueous ethanol medium at 303K. The reactions show unit order dependence with respect to [Benzophenoneoxime].The reaction is acid catalyzed, the effect of concentration of Mangnoussulphate, sodium perchlorate and dielectric constant on the reaction rates was studied, Thermodynamic parameters were calculated from the Eyring?s plot. Mechanism consistent with the observed kinetic results has been proposed and the related rate law derived.

Kinetics mechanism Benzophenoneoxime Bispyridinesilver (I) dichromate.